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| 10.10.2020 | 19:00 | Waasland-Beveren | - | KFC Sparta Petegem | 3:0 (1:0) | |
| 19:30 | KVV THES Sport Tessenderlo | - | SK Deinze | 3:1 (1:0, 1:1) pró. | ||
| 20:00 | City Pirates Merksem | - | Rupel Boom FC | 1:2 (1:1) | ||
| 20:00 | KSC Lokeren-Temse | - | VC Jong Lede | 2:0 (1:0) | ||
| 11.10.2020 | 15:00 | Olympic Charleroi | - | Eendracht Aalst | 2:1 (1:1, 1:1) pró. | |
| 16:00 | URSL Visé | - | KFC Dessel Sport | 1:2 (1:1, 1:1) pró. | ||
| 16:00 | KSK Tongeren | - | Union Saint-Ghislain Tertre-Hautrage | 3:0 (1:0) | ||
| 16:00 | Lommel SK | - | KVV Zelzate | 3:2 (1:1) | ||
| 16:00 | Union Saint-Gilloise | - | KSK Heist | 4:0 (1:0) | ||
| 16:00 | KVC Westerlo | - | RC Hades | 5:1 (3:0) | ||
| 16:00 | Olsa Brakel | - | FCV Dender EH | 2:0 (0:0) | ||
| 16:00 | RFC Seraing | - | KSC Blankenberge | 6:1 (4:0) | ||
| 16:00 | RFC Warnant | - | RFC Liège | 0:1 (0:1) | ||
| 16:00 | RAA La Louviére | - | RSD Jette | 2:0 (1:0) | ||
| 16:00 | Royal Knokke FC | - | Oud-Heverlee Leuven | 0:2 (0:1) | ||
| 17:00 | RJ Rochefortoise FC | - | RWD Molenbeek | 1:8 (0:4) |
