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| 11.05.1991 | Real Madrid | - | Athletic | 4:1 (2:1) | ||
| CD Logroñés | - | Sporting | 1:2 (1:0) | |||
| Cádiz CF | - | Barcelona | 4:0 (3:0) | |||
| 12.05.1991 | Real Oviedo | - | Osasuna | 0:0 (0:0) | ||
| Espanyol | - | Tenerife | 1:0 (1:0) | |||
| Betis | - | Real Burgos | 0:0 (0:0) | |||
| Zaragoza | - | CD Castellón | 2:0 (1:0) | |||
| Mallorca | - | Sevilla | 1:1 (0:0) | |||
| Valencia | - | Valladolid | 2:0 (1:0) | |||
| Real Sociedad | - | Atlético | 2:1 (1:1) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Barcelona | 34 | 24 | 6 | 4 | 71:29 | 42 | 54:14 |
| 2 |
|
Atlético | 34 | 16 | 13 | 5 | 48:19 | 29 | 45:23 |
| 3 |
|
Osasuna | 34 | 13 | 14 | 7 | 38:29 | 9 | 40:28 |
| 4 |
|
Real Madrid | 34 | 17 | 5 | 12 | 54:33 | 21 | 39:29 |
| 5 |
|
Sporting | 34 | 14 | 11 | 9 | 45:35 | 10 | 39:29 |
| 6 |
|
Sevilla | 34 | 14 | 8 | 12 | 41:41 | 0 | 36:32 |
| 7 |
|
Real Oviedo | 34 | 11 | 14 | 9 | 30:35 | -5 | 36:32 |
| 8 |
|
Valencia | 34 | 13 | 9 | 12 | 39:37 | 2 | 35:33 |
| 9 |
|
CD Logroñés | 34 | 12 | 10 | 12 | 26:29 | -3 | 34:34 |
| 10 |
|
Real Burgos | 34 | 9 | 15 | 10 | 29:25 | 4 | 33:35 |
| 11 |
|
Athletic | 34 | 14 | 5 | 15 | 35:46 | -11 | 33:35 |
| 12 |
|
Valladolid | 34 | 10 | 12 | 12 | 35:38 | -3 | 32:36 |
| 13 |
|
Real Sociedad | 34 | 10 | 12 | 12 | 35:42 | -7 | 32:36 |
| 14 |
|
Espanyol | 34 | 11 | 9 | 14 | 35:41 | -6 | 31:37 |
| 15 |
|
Tenerife | 34 | 13 | 5 | 16 | 34:49 | -15 | 31:37 |
| 16 |
|
Mallorca | 34 | 9 | 12 | 13 | 29:37 | -8 | 30:38 |
| 17 |
|
Zaragoza | 34 | 10 | 9 | 15 | 31:35 | -4 | 29:39 |
| 18 |
|
Cádiz CF | 34 | 5 | 14 | 15 | 25:37 | -12 | 24:44 |
| 19 |
|
CD Castellón | 34 | 7 | 10 | 17 | 24:44 | -20 | 24:44 |
| 20 |
|
Betis | 34 | 6 | 11 | 17 | 35:58 | -23 | 23:45 |
