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| 24.09.1994 | CD Logroñés | - | Albacete | 1:1 (0:0) | ||
| Real Madrid | - | Athletic | 4:0 (3:0) | |||
| Deportivo | - | Espanyol | 1:1 (0:1) | |||
| Barcelona | - | SD Compostela | 4:0 (1:0) | |||
| Valladolid | - | Zaragoza | 2:0 (0:0) | |||
| 25.09.1994 | Real Sociedad | - | Valencia | 0:2 (0:1) | ||
| Betis | - | Sporting | 5:0 (1:0) | |||
| Celta | - | Real Racing | 2:1 (0:0) | |||
| Tenerife | - | Sevilla | 0:0 (0:0) | |||
| Real Oviedo | - | Atlético | 1:0 (0:0) |
| » Clasificación | En casa | Fuera de casa | 1.ª vuelta | 2.ª vuelta | 1.ª parte | 2.ª parte |
| # | Equipo | P | V | E | D | Goles | DG | Pun. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 4 | 3 | 1 | 0 | 11:2 | 9 | 7:1 |
| 2 |
|
Deportivo | 4 | 3 | 1 | 0 | 7:3 | 4 | 7:1 |
| 3 |
|
Espanyol | 4 | 2 | 2 | 0 | 9:3 | 6 | 6:2 |
| 4 |
|
Valencia | 4 | 3 | 0 | 1 | 8:4 | 4 | 6:2 |
| 5 |
|
Betis | 4 | 2 | 1 | 1 | 9:2 | 7 | 5:3 |
| 6 |
|
Barcelona | 4 | 2 | 1 | 1 | 7:3 | 4 | 5:3 |
| 7 |
|
Celta | 4 | 1 | 3 | 0 | 4:3 | 1 | 5:3 |
| 8 |
|
Zaragoza | 4 | 2 | 1 | 1 | 6:6 | 0 | 5:3 |
| 9 |
|
Sevilla | 4 | 2 | 1 | 1 | 3:4 | -1 | 5:3 |
| 10 |
|
Tenerife | 4 | 1 | 2 | 1 | 4:4 | 0 | 4:4 |
| 11 |
|
Real Oviedo | 4 | 1 | 1 | 2 | 6:8 | -2 | 3:5 |
| 12 |
|
Albacete | 4 | 0 | 3 | 1 | 4:7 | -3 | 3:5 |
| 13 |
|
Valladolid | 4 | 1 | 1 | 2 | 2:5 | -3 | 3:5 |
| 14 |
|
SD Compostela | 4 | 1 | 1 | 2 | 3:8 | -5 | 3:5 |
|
Sporting | 4 | 1 | 1 | 2 | 3:8 | -5 | 3:5 | |
| 16 |
|
Athletic | 4 | 1 | 1 | 2 | 2:7 | -5 | 3:5 |
| 17 |
|
Real Sociedad | 4 | 1 | 0 | 3 | 4:6 | -2 | 2:6 |
| 18 |
|
Atlético | 4 | 1 | 0 | 3 | 4:7 | -3 | 2:6 |
| 19 |
|
CD Logroñés | 4 | 0 | 2 | 2 | 1:4 | -3 | 2:6 |
| 20 |
|
Real Racing | 4 | 0 | 1 | 3 | 3:6 | -3 | 1:7 |
