| 1. Jornada | 25.08.2012 | US Grosseto FC | - | Novara Calcio | 1:1 |  |
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| 3. Jornada | 09.09.2012 | Calcio Padova | - | US Grosseto FC | 1:1 |  |
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| 4. Jornada | 15.09.2012 | US Grosseto FC | - | FC Crotone | 1:0 | ||||
| 5. Jornada | 22.09.2012 | Virtus Lanciano | - | US Grosseto FC | 1:1 | ||||
| 6. Jornada | 25.09.2012 | US Grosseto FC | - | Juve Stabia | 2:2 | |
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| 7. Jornada | 29.09.2012 | Vicenza Calcio | - | US Grosseto FC | 2:1 | ||||
| 10. Jornada | 20.10.2012 | Modena FC | - | US Grosseto FC | 0:0 | |
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| 12. Jornada | 30.10.2012 | AC Cesena | - | US Grosseto FC | 3:2 | ||||
| 13. Jornada | 03.11.2012 | US Grosseto FC | - | Ascoli Calcio | 2:1 | |
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| 14. Jornada | 09.11.2012 | US Grosseto FC | - | Spezia Calcio | 1:1 | ||||
| 15. Jornada | 17.11.2012 | Empoli | - | US Grosseto FC | 3:2 |  |
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| 16. Jornada | 24.11.2012 | US Grosseto FC | - | Brescia Calcio | 2:2 | ||||
| 17. Jornada | 01.12.2012 | AS Livorno | - | US Grosseto FC | 4:0 | ||||
| 18. Jornada | 08.12.2012 | US Grosseto FC | - | Pro Vercelli | 3:0 | ||||
| 19. Jornada | 19.01.2013 | AS Varese 1910 | - | US Grosseto FC | 4:0 |
Italia