| Primera etapa | 14.09.2006 | AS Livorno | - | FC Superfund | 2:0 |  |
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| Grupo A | 19.10.2006 | AS Livorno | - | Rangers FC | 2:3 | |
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| Grupo A | 02.11.2006 | Partizan | - | AS Livorno | 1:1 | ||||
| Grupo A | 29.11.2006 | AS Livorno | - | Maccabi Haifa | 1:1 | |
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| Grupo A | 14.12.2006 | AJ Auxerre | - | AS Livorno | 0:1 | |
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| Tercera ronda | 14.02.2007 | AS Livorno | - | Espanyol | 1:2 | ||||
| Tercera ronda | 22.02.2007 | Espanyol | - | AS Livorno | 2:0 |
Italia