| 1. Jornada | 25.08.2013 | AS Livorno | - | Roma | 0:2 | ||||
| 7. Jornada | 06.10.2013 | Nápoles | - | AS Livorno | 4:0 | ||||
| 8. Jornada | 20.10.2013 | AS Livorno | - | Sampdoria | 1:2 | ||||
| 9. Jornada | 27.10.2013 | Bolonia | - | AS Livorno | 1:0 |  |
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| 10. Jornada | 30.10.2013 | AS Livorno | - | Torino | 3:3 | ||||
| 11. Jornada | 03.11.2013 | AS Livorno | - | Atalanta | 1:0 | ||||
| 13. Jornada | 24.11.2013 | AS Livorno | - | Juventus | 0:2 | ||||
| 14. Jornada | 01.12.2013 | Chievo | - | AS Livorno | 3:0 | ||||
| 19. Jornada | 11.01.2014 | AS Livorno | - | Parma FC | 0:3 | ||||
| 20. Jornada | 18.01.2014 | Roma | - | AS Livorno | 3:0 | ||||
| 23. Jornada | 09.02.2014 | AS Livorno | - | Génova | 0:1 | |
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| 27. Jornada | 09.03.2014 | Sampdoria | - | AS Livorno | 4:2 | ||||
| 29. Jornada | 22.03.2014 | Torino | - | AS Livorno | 3:1 | ||||
| 32. Jornada | 07.04.2014 | Juventus | - | AS Livorno | 2:0 | ||||
| 33. Jornada | 13.04.2014 | AS Livorno | - | Chievo | 2:4 | ||||
| 34. Jornada | 19.04.2014 | Milan | - | AS Livorno | 3:0 | ||||
| 35. Jornada | 27.04.2014 | AS Livorno | - | Lazio | 0:2 | ||||
| 36. Jornada | 04.05.2014 | Udinese | - | AS Livorno | 5:3 | ||||
| 37. Jornada | 11.05.2014 | AS Livorno | - | Fiorentina | 0:1 | ||||
| 38. Jornada | 18.05.2014 | Parma FC | - | AS Livorno | 2:0 |
Italia
