| 2. Jornada | 12.09.2020 | SK Dnipro-1 | - | Olimpik Donetsk | 1:3 | ||||
| 3. Jornada | 20.09.2020 | Olimpik Donetsk | - | FC Mynai | 3:0 | ||||
| 4. Jornada | 27.09.2020 | Shakhtar Donetsk | - | Olimpik Donetsk | 2:0 | ||||
| 6. Jornada | 18.10.2020 | Olimpik Donetsk | - | Vorskla Poltava | 0:1 |  |
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| 7. Jornada | 24.10.2020 | Olimpik Donetsk | - | Desna Chernigov | 0:2 | ||||
| 8. Jornada | 31.10.2020 | Kolos Kovalivka | - | Olimpik Donetsk | 1:2 | ||||
| 12. Jornada | 06.12.2020 | Olimpik Donetsk | - | Rukh Lviv | 3:1 | ||||
| 13. Jornada | 11.12.2020 | Olimpik Donetsk | - | FK Lviv | 1:1 | |
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| 14. Jornada | 13.02.2021 | Dinamo Kiev | - | Olimpik Donetsk | 3:1 |  |
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| 15. Jornada | 22.02.2021 | Olimpik Donetsk | - | SK Dnipro-1 | 0:2 | ||||
| 18. Jornada | 14.03.2021 | FK Oleksandriya | - | Olimpik Donetsk | 2:0 | ||||
| 19. Jornada | 20.03.2021 | Vorskla Poltava | - | Olimpik Donetsk | 3:0 | ||||
| 21. Jornada | 11.04.2021 | Olimpik Donetsk | - | Kolos Kovalivka | 1:2 | ||||
| 25. Jornada | 06.05.2021 | Rukh Lviv | - | Olimpik Donetsk | 3:0 | ||||
| 26. Jornada | 09.05.2021 | FK Lviv | - | Olimpik Donetsk | 1:1 | |
Argentina