| 10. Jornada | 24.09.2005 | Zakarpattya Uzhgorod | - | Shakhtar Donetsk | 0:3 | ||||
| 12. Jornada | 16.10.2005 | Vorskla Poltava | - | Shakhtar Donetsk | 0:2 | ||||
| 13. Jornada | 23.10.2005 | Shakhtar Donetsk | - | Metalurh Donetsk | 2:0 | ||||
| 16. Jornada | 20.11.2005 | Shakhtar Donetsk | - | Volyn Lutsk | 2:0 | ||||
| 17. Jornada | 27.11.2005 | Dnipro Dnipropetrovsk | - | Shakhtar Donetsk | 2:2 |  |
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| 18. Jornada | 05.12.2005 | Shakhtar Donetsk | - | FK Kharkiv | 3:0 | ||||
| 20. Jornada | 05.03.2006 | Shakhtar Donetsk | - | Tavriya Simferopol (1958-2014) | 1:1 | ||||
| 22. Jornada | 19.03.2006 | Metalurg Zaporizhya | - | Shakhtar Donetsk | 0:3 | ||||
| 23. Jornada | 25.03.2006 | Shakhtar Donetsk | - | Arsenal Kiev | 1:0 | ||||
| 25. Jornada | 09.04.2006 | Shakhtar Donetsk | - | Zakarpattya Uzhgorod | 3:0 | ||||
| 26. Jornada | 16.04.2006 | FK Illichivets | - | Shakhtar Donetsk | 1:2 | ||||
| 28. Jornada | 30.04.2006 | Metalurh Donetsk | - | Shakhtar Donetsk | 1:3 | ||||
| 29. Jornada | 06.05.2006 | Shakhtar Donetsk | - | Chernomorets Odessa | 2:0 |
Nigeria