| 8. Jornada | 01.09.2012 | Karpaty Lviv | - | Metalurh Donetsk | 0:1 | ||||
| 9. Jornada | 16.09.2012 | Metalurh Donetsk | - | Arsenal Kiev | 5:0 | ||||
| 10. Jornada | 30.09.2012 | Hoverla Uzhgorod | - | Metalurh Donetsk | 2:1 | ||||
| 11. Jornada | 05.10.2012 | Metalurh Donetsk | - | FK Krivbas (old) | 6:2 | ||||
| 12. Jornada | 20.10.2012 | Volyn Lutsk | - | Metalurh Donetsk | 1:1 |  |
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| 13. Jornada | 27.10.2012 | Metalurh Donetsk | - | Vorskla Poltava | 0:0 | ||||
| 14. Jornada | 04.11.2012 | Chernomorets Odessa | - | Metalurh Donetsk | 3:0 | |
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| 15. Jornada | 11.11.2012 | Metalurh Donetsk | - | Shakhtar Donetsk | 0:4 | ||||
| 16. Jornada | 17.11.2012 | Metalurh Donetsk | - | Dinamo Kiev | 1:0 | ||||
| 17. Jornada | 24.11.2012 | Zorya Lugansk | - | Metalurh Donetsk | 1:2 | |
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| 20. Jornada | 08.03.2013 | Metalurh Donetsk | - | FK Illichivets | 0:0 | ||||
| 22. Jornada | 30.03.2013 | Metalurh Donetsk | - | Metalurg Zaporizhya | 2:0 | ||||
| 25. Jornada | 20.04.2013 | Metalurh Donetsk | - | Hoverla Uzhgorod | 2:1 | ||||
| 26. Jornada | 28.04.2013 | FK Krivbas (old) | - | Metalurh Donetsk | 1:1 |  |
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| 30. Jornada | 26.05.2013 | Shakhtar Donetsk | - | Metalurh Donetsk | 4:0 | |
Armenia