| 8. Jornada | 20.10.2013 | AS Livorno | - | Sampdoria | 1:2 | ||||
| 12. Jornada | 09.11.2013 | Inter | - | AS Livorno | 2:0 | ||||
| 18. Jornada | 05.01.2014 | Fiorentina | - | AS Livorno | 1:0 | ||||
| 19. Jornada | 11.01.2014 | AS Livorno | - | Parma FC | 0:3 | ||||
| 20. Jornada | 18.01.2014 | Roma | - | AS Livorno | 3:0 | ||||
| 21. Jornada | 26.01.2014 | AS Livorno | - | Sassuolo | 3:1 |  |
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| 22. Jornada | 02.02.2014 | Calcio Catania | - | AS Livorno | 3:3 |  |
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| 23. Jornada | 09.02.2014 | AS Livorno | - | Génova | 0:1 | ||||
| 24. Jornada | 16.02.2014 | Cagliari Calcio | - | AS Livorno | 1:2 |  |
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| 26. Jornada | 02.03.2014 | AS Livorno | - | Nápoles | 1:1 | |
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| 27. Jornada | 09.03.2014 | Sampdoria | - | AS Livorno | 4:2 | ||||
| 28. Jornada | 16.03.2014 | AS Livorno | - | Bolonia | 2:1 | |
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| 29. Jornada | 22.03.2014 | Torino | - | AS Livorno | 3:1 | ||||
| 30. Jornada | 26.03.2014 | Atalanta | - | AS Livorno | 2:0 | ||||
| 31. Jornada | 31.03.2014 | AS Livorno | - | Inter | 2:2 | ||||
| 32. Jornada | 07.04.2014 | Juventus | - | AS Livorno | 2:0 | ||||
| 33. Jornada | 13.04.2014 | AS Livorno | - | Chievo | 2:4 | |
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| 34. Jornada | 19.04.2014 | Milan | - | AS Livorno | 3:0 | ||||
| 36. Jornada | 04.05.2014 | Udinese | - | AS Livorno | 5:3 | ||||
| 37. Jornada | 11.05.2014 | AS Livorno | - | Fiorentina | 0:1 | |
Italia
