| 1. Jornada | 25.08.2013 | AS Livorno | - | Roma | 0:2 |  |
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| 2. Jornada | 01.09.2013 | Sassuolo | - | AS Livorno | 1:4 | ||||
| 3. Jornada | 15.09.2013 | AS Livorno | - | Calcio Catania | 2:0 | |
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| 4. Jornada | 21.09.2013 | Génova | - | AS Livorno | 0:0 | ||||
| 5. Jornada | 25.09.2013 | AS Livorno | - | Cagliari Calcio | 1:1 | ||||
| 6. Jornada | 29.09.2013 | Hellas Verona | - | AS Livorno | 2:1 | |
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| 7. Jornada | 06.10.2013 | Nápoles | - | AS Livorno | 4:0 | ||||
| 8. Jornada | 20.10.2013 | AS Livorno | - | Sampdoria | 1:2 | ||||
| 9. Jornada | 27.10.2013 | Bolonia | - | AS Livorno | 1:0 | ||||
| 10. Jornada | 30.10.2013 | AS Livorno | - | Torino | 3:3 | |
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| 12. Jornada | 09.11.2013 | Inter | - | AS Livorno | 2:0 | |
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| 13. Jornada | 24.11.2013 | AS Livorno | - | Juventus | 0:2 | ||||
| 14. Jornada | 01.12.2013 | Chievo | - | AS Livorno | 3:0 | ||||
| 15. Jornada | 07.12.2013 | AS Livorno | - | Milan | 2:2 | ||||
| 16. Jornada | 15.12.2013 | Lazio | - | AS Livorno | 2:0 | |
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| 17. Jornada | 21.12.2013 | AS Livorno | - | Udinese | 1:2 | |
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| 18. Jornada | 05.01.2014 | Fiorentina | - | AS Livorno | 1:0 | |
Italia