| Primera | 11.11.06 | Atlético | - | Villarreal | 3:1 |  |
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| Primera | 08.04.07 | Villarreal | - | Atlético | 0:1 | ||||
| Primera | 04.11.07 | Atlético | - | Villarreal | 3:4 | |
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| Primera | 29.03.08 | Villarreal | - | Atlético | 3:0 | ||||
| Primera | 15.03.09 | Atlético | - | Villarreal | 3:2 | |
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| Primera | 17.04.10 | Villarreal | - | Atlético | 2:1 | |
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| Primera | 24.10.10 | Villarreal | - | Atlético | 2:0 | ||||
| Primera | 05.03.11 | Atlético | - | Villarreal | 3:1 | |
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| Ch. League | 18.10.11 | Manchester City | - | Villarreal | 2:1 | |
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| Ch. League | 02.11.11 | Villarreal | - | Manchester City | 0:3 |
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