| 1. Jornada | 15.07.2000 | Basilea | - | FC Sion | 4:1 | ||||
| 2. Jornada | 18.07.2000 | FC Sion | - | Grasshopper Club Zürich | 1:0 | ||||
| 3. Jornada | 22.07.2000 | Yverdon Sport FC | - | FC Sion | 0:1 | ||||
| 4. Jornada | 29.07.2000 | FC Sion | - | Servette FC | 1:0 |  |
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| 6. Jornada | 12.08.2000 | FC Sion | - | FC Aarau | 0:1 | ||||
| 8. Jornada | 26.08.2000 | FC Sion | - | FC Zürich | 3:3 |  |
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| 9. Jornada | 05.09.2000 | Lausanne Sports | - | FC Sion | 3:2 | ||||
| 15. Jornada | 21.10.2000 | Servette FC | - | FC Sion | 0:1 | ||||
| 14. Jornada | 24.10.2000 | FC Sion | - | Yverdon Sport FC | 0:0 | ||||
| 16. Jornada | 28.10.2000 | FC Sion | - | FC Lugano | 3:2 | ||||
| 17. Jornada | 01.11.2000 | FC Aarau | - | FC Sion | 1:1 |  |
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| 18. Jornada | 05.11.2000 | FC Sion | - | FC St. Gallen | 2:1 | ||||
| 19. Jornada | 19.11.2000 | FC Zürich | - | FC Sion | 1:3 | |
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| 20. Jornada | 26.11.2000 | FC Sion | - | Lausanne Sports | 0:1 | ||||
| 21. Jornada | 03.12.2000 | FC Sion | - | FC Luzern | 3:0 | ||||
| 22. Jornada | 10.12.2000 | Neuchâtel Xamax FC | - | FC Sion | 1:0 |
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