| 2. Jornada | 21.08.2022 | Athletic | - | Valencia | 1:0 | ||||
| 4. Jornada | 04.09.2022 | Athletic | - | Espanyol | 0:1 |  |
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| 11. Jornada | 23.10.2022 | Barcelona | - | Athletic | 4:0 | ||||
| 12. Jornada | 30.10.2022 | Athletic | - | Villarreal | 1:0 | ||||
| 13. Jornada | 04.11.2022 | Girona | - | Athletic | 2:1 | ||||
| 14. Jornada | 08.11.2022 | Athletic | - | Valladolid | 3:0 | |
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| 24. Jornada | 05.03.2023 | Rayo | - | Athletic | 0:0 | ||||
| 30. Jornada | 22.04.2023 | Almería | - | Athletic | 1:2 | ||||
| 31. Jornada | 27.04.2023 | Athletic | - | Sevilla | 0:1 | ||||
| 38. Jornada | 04.06.2023 | Real Madrid | - | Athletic | 1:1 |
España